While I agree that the words "Absolutely Not" are indeed a very rude response, I think you crossed the line by asking your nanny this favor.
Your relationship is a professional one first and foremost, but also you have asked her a HUGE favor. Her car is her bread and butter OP. When if your dad wrecked her car, then what would you guys do? Plus, it would damage your relationship with each other and I am sure you do not want that hanging over your heads.
Why not just have your Dad rent a vehicle while he is here and keep your nanny out of it?
It is best not to involve her anyway since this really is not her issue or has anything to do with her.
I would be shocked if my family asked this of me.