Man people are harsh on here, although they are right. OP you need to know what you deserve and demand it. You can sit down with them and say something along the lines of:
"I've enjoyed working for you the last 6 years, however I have one concern that I need to address. I took this job with the expectation that I would receive annual raises. I've tried to be understanding of your situation and so I have not pursued it in the past. However, I need to look out for myself and if we are unable to come to an agreement about raising my salary, then I will have to reconsider my position as your Nanny."
Also you have to mean it! They may refuse, and then you have to be prepared to look for another job. This happened to me at my last job, I asked for a raise, they said no, I said OK, two weeks later I gave notice after securing a new job with better pay. I don't work in an area where there is a big demand for nannies but I was able to do it.
Good luck and please update us!