OP here - thanks for all of these great ideas. I am going to go with the above advice to do bookcases on either side of a desk. Possibly there will be room for a comfy chair in there but I'll have to see once shelves/desk are installed. I saw in another thread that expedit is being discontinued, so I plan to get those in a hurry

I'd like the look to mimic built ins, so do you suggest I go with the white expedit or high gloss white? Maybe I'll have a better sense when I see them in person, but the crown mouldings in the room are painted a a slightly glossy white (typical trim finish - not flat but not high gloss), so I'm not sure which will look better.