What express lanes are you talking about?
Outside the beltway, 66 has one HOV Lane. Yes, it will save you time, but not a ton. Hard to estimate. It’s not physically separate, just the left lane is reserved for HOV. From where you are starting, this is only Nutley to the beltway, which is one exit - won’t make a huge difference.
Inside the beltway, all of 66 is HOT (HOV or toll) during rush hour. There’s no express lanes vs regular, it’s all the same. The estimates you are seeing assume that you’ll either be a carpool or paying $$$ to use those same lanes.
Will you be on the beltway for part of it? That does have separate HOT lanes from the regular lanes.