Salt Mines --tour underground and big slides, etc. These are near Salzburg/Berchtesgaden
Ludwig castles:
Palace at Chiemsee
Neuschwanstein ("disney castle)
Linderhof Palace
All are interesting and fun.
6 year old would prefer Neuschwanstein and, probably, the castle in Salzburg
https://www.european-traveler.com/germany/visiting-schloss-linderhof-and-park-bavaria/
Science Museum in Munich