Baseball game.
Baltimore aquarium or Baltimore science museum, then dinner.
Trip to bookstore and they can each spend $x, then go for froyo.
Boat ride along river, then froyo. Or take water taxi to Alexandria (if you're in DC or MD) and have lunch.
Trip to Tysons mall: Lego store, amazing candy store, movie, lunch at that sushi place in the walkway area that has the revolving belt of food.