"A 2006 issue of the “Journal of Agricultural and Food Chemistry” found that between 5 to 25 percent of vitamin C content was lost in cut pieces of kiwi, pineapple, mango, strawberry, watermelon and cantaloupe over a period of six days when the fruits were stored at 41 degrees Fahrenheit. There was also a significant loss of carotenoids."
http://www.livestrong.com/article/548978-does-fruit-lose-its-nutritional-value-when-its-blended/
Oxidization causes the loss of nutrients overtime, so making the smoothies ahead of time is not the best option.