Listen, offer to help. If she has sole custody offer a play date; if they have shared custody, invite her out sometime when she doesn't have the kids, just the two of you, if you're up for lending an ear. If she's talking about this stuff to someone she doesn't know well, it's a good bet she's feeling alone and reaching out to connect with you. Being separated is lonely, overwhelming, and so many other things, and if you have it in you to offer support it would be a phenomenally kind thing to do.