East Potomac Tennis Center has a 10 and under tennis program, and I think that they offer it to the 3-5 set as well. I really like 10 and under tennis - it's geared to them, and my kids seem to really enjoy it.
eastpotomactennis.com
Also, WTEF has a 10 and under program and they have classes as well at Rock Creek Tennis Center. www.wtef.org.
Good Luck!