There's a new school that has a program very similar to Christian Family (Montessori, Catholic) opening in SW right near the Nats stadium. I'm not sure about part time options, but since there's new there could be some flexibility. It's called Waterside Academy and the website is (I think) www.watersideacademy.org. They are taking kids from ages 3-9 for next year (maybe younger than 3, almost 3 the way Christian Family does). I am not sure the exact location, but I imagine it must be near Navy Yard Metro station so on the green line like Petworth.