I agree that your best bet is to rent first to get a sense of the area, particularly if you'll be moving here a while before your child will start kindergarden.
I've heard good things about Olney, MD, and there might be things in your range.
http://www.realtor.com/realestateandhomes-search/Olney_MD/price-0-300000
Generally speaking, Prince George's County, MD and DC (although there is variation within them) don't have good public schools. Almost all of the other surrounding counties have good school systems, especially when compared to other areas. Some people on DCUM feel that only the neighborhoods with $1m homes have good public schools, but I don't think that's true.
I'm curious about what kind of business you have that location does not seem to be a factor at all--something entirely internet based?