I have some Easton Press that I bought second hand and some Folio Society. The Folio Society books, in particular, are really beautiful.
I also love the Collector's Library classics that are hardback and small - maybe 6x4 inches? I have one whole shelf of those.
I collect NYRB publications, which are always interesting books - many under-published 20th century books and books in translation. I've found some true favorites through their publications. They have different colored spines and look fantastic on the shelf.
And I collect Persephone grey covers. Their books are mainly by women, predominantly British women from the 19th and 20th century. I've loved all of the ones I've read.