No, you're not going to be able to register it as a new car in VA if it doesn't meet VA's new car emissions requirements (i.e. CARB standards), regardless of where it was purchased.

Looks like certain models (RT/SRT) won't be sold in Virginia due to CARB compliance. Is it possible to buy the Durango from out of state and then register it in VA?

https://www.caranddriver.com/news/a66107920/2026-dodge-durango-rt-hellcat-cant-be-sold-carb-states/