There are ways to do this. Excepted hiring authority (schedule A, agency authority, job category authority) or non-competitive eligibility on the applicant's side (veterans). Waiver of competition for special qualifications or urgent need. A blanket open announcement (some are open for years), or a recent announcement that allowed for multiple selections. There are others means. None of these are common and many hiring managers/ HR people will not have experience with them.
If you're asking if you can pick a destination and then come in through the back door, the answer is that it all depends on how much the receiving office wants you. Hiring someone through most of the methods above requires a lot of effort from a lot of people. Again, it is not common.