Ok, how old a machine?
If > 5 years old, the 'donation' level to some charity or school is rather minimal. Your donation is probably to an electronics recycler bin. If this is the case, take out the hard drive, physically using a screwdriver, and smash it with a hammer or power drill and throwing that bit in the bin.
If you want to donate to a school, you'll probably need to give them a machine with hard drive and operating system already, so you may have a slight expense and reinstallation process (which depending on the machine may or may not be worth it).
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